Planning (a) and (b) in Chemistry Internal Assessment

The following list of investigation titles is divided into two groups:

  1. experiments suitable for planning (a) and (b)
  2. experiments suitable for planning (b) only.

For each title, a list of the possible variables is included. Experiments suitable for planning (a) have at least two independent variables that could be manipulated during an investigation. The titles are sufficiently specific to give candidates a sense of direction, but they are not sufficiently specific to serve as a research question. Candidates will have to modify the statement to make it more specific and focused. In most cases, this will involve indicating the variable(s) chosen for investigation. Where the title completely specifies the problem, and only one or no variables can be manipulated, the experiment is listed for planning (b) only. If the experiment is to be used to assess planning (a), candidates should not be given information about the possible variables, since one aspect of planning (a) concerns the candidate's ability to select the relevant variables without help from the teacher.

Variables are things we measure, control or manipulate in an investigation. Independent variables are those that are manipulated, whereas dependent variables are measured or registered. The variable that is selected for manipulation is independent, the variable that depends on the manipulation is dependent. Thus, in a calorimetry investigation, where a candidate measures the temperature every 30 seconds, time is the independent variable, and temperature is the dependent variable. Similarly, in a rate investigation, where the candidate measures the times taken to collect certain volumes of gas, volume is independent, and time is dependent.

Investigations Suitable for Planning (a) and (b)

Click here for a description of the planning criteria.

1. Investigate the volume of a drop

Dependent: Volume or mass of liquid
Independent: Nature of liquid, includes mass, density, viscosity (these cannot be separated)
  Temperature
  Material of dropper
  Size of opening
  Angle of delivery
  Speed of delivery
  Height of water column
  Pressure (external)

Note: This is a very simple experiment suitable as a first exposure to practise the skills associated with planning (a) and (b). Any of the first seven independent variables can be investigated.

2. Investigate the height of a liquid in a capillary tube

Dependent: Height of liquid
Independent: Nature of liquid
  Diameter of tube
  Material of tube
  Angle of tube
  Temperature
  Overall length of tube
  Depth of capillary tube in the liquid

Note: Suitable for practice for planning (a) and (b). Any of the independent variables could be tested.

3. Investigate factors influencing the solubility of salts

Dependent: Mass of solute
Independent: Volume or mass of water
  Temperature
  Anion
  Cation
  Relation of charges of the ions

Note: Candidates will probably control the first independent variable and can manipulate any of the last three.

4. Investigate the catalysed decomposition of hydrogen peroxide

Dependent: Some measure of change of concentration of a reactant or product (volume of gas, decrease in mass, or concentration of hydrogen peroxide)
Independent: Relative quantity of catalyst
  Concentration of hydrogen peroxide
  Other transition metal oxides
  Other manganese compounds
  Oxides or metals
  State of division
  Heterogeneous or homogeneous catalysis
  Temperature

Note: Temperature will probably be controlled. Any of the other independent variables can be investigated.

5. Investigate exposure to radiation

Dependent: Counts per unit time
Independent: Type of radiation
  Type of barrier
  Thickness of barrier
  Distance between source and detector
  Strength of magnetic field
  Angle between detector and source
  Time of counting
  Temperature

Note: Any of the independent variables can be easily manipulated, apart from temperature which will probably be controlled.

6. Investigate the rate of electroplating a metal

Dependent: Quantity of metal deposited
Independent: Time
  Temperature
  Concentration of solution
  Identity of metal
  Size of electrode
  Voltage
  Current

Note: Any of the independent variables could be investigated.

7. Investigate the equilibrium reaction between an alkanoic acid and an alkanol

Dependent: Quantity of ester (or change in concentration of acid or alkanol)
Independent: Initial concentrations of acid and alkanol
  Time elapsed
  Temperature
  Nature of acid
  Nature of alkanol
  Method of measurement

Note: Any of the first five independent variables could be manipulated, but this presents a difficult and time-consuming experiment. It would be easier for the teacher to direct the candidates to measure the amounts of acid, and to grade this for planning (b) only.

8. Investigate the effect of acid rain on building materials

Dependent: Effect on material
Independent: Type of material
  Time of exposure
  Surface area exposed
  Method of measurement
  Temperature
  Nature of acid
  Concentration of acid
  Nature of exposure

Note: Any of the independent variables could be investigated.

9. Investigate the conditions affecting the rate of escape of carbon dioxide from soda water

Dependent: Quantity of gas released
Independent: Time
  Temperature
  Amount of soda water
  Depth of soda water
  Surface area of soda water
  Material of container
  Extent of agitation of the soda water
  Pressure

Note: Any of the first seven independent variables could be investigated.

10. Investigate the amount of a solid that will dissolve in a solvent

Dependent: Quantity of solid
Independent: Nature of solid
  Quantity of solvent
  Nature of solvent
  Time
  Order of addition
  Temperature
  Stirring
  State of division

Note: Any of the independent variables could be investigated. The effect of the last three is probably known in advance.

11. Investigate the factors influencing the voltage of an electrochemical cell

Dependent: Voltage
Independent: Size of electrodes
  Distance between electrodes
  Nature of electrodes
  Nature of solution
  Concentration of solution
  Method of measurement
  Nature of ion transfer (salt bridge)

Note: Any of the first five independent variables could be investigated.

12. Investigate the factors affecting retention in paper chromatography

Dependent: Distance travelled by spot
Independent: Thickness of paper
  Nature of paper
  Eluting solvent
  Size of spot
  Concentration of solute
  Distance solvent travels
  Nature of solute
  Temperature

Note: Any of the first six independent variables could be manipulated.

13. Investigate testing the energy from liquid fuels

Dependent: Temperature change of water
Independent: Construction of calorimeter (including nature of water container, amount and location of insulation, supply of oxygen)
  Type of fuel
  Amount of fuel/time of burning
  Amount of water
  Distance of flame from calorimeter

Note: The first set of independent variables will be manipulated, and perhaps also the type of fuel. The last three independent variables will need to be controlled.

14. Investigate the factors affecting the rate of a reaction

Dependent: Change in concentration
Independent: Nature of reaction
  Concentration of reagents
  Total volume
  Temperature
  State of division (only for heterogeneous reaction)
  Catalysis

Note: Once a candidate chooses a reaction, at least two other independent variables could be manipulated.

15. Determine a property of a gas

Dependent: Measurements
Independent: Property investigated
  Temperature
  Volume
  Pressure
  Amount of gas

Note: The property chosen should be one where a variable can be changed. Candidates should have to devise their own methods, rather than following familiar techniques.

16. Investigate the factors that affect the rate of the reaction between sodium thiosulfate and hydrochloric acid

Dependent: Time for visual change
Independent: Total volume of solution
  Concentration of sodium thiosulfate
  Concentration of hydrochloric acid
  Temperature

Note: Several variables could be manipulated. This is a very simple variation on investigation 14 (above).

Investigations Suitable for Planning (b) Only

1. Investigate reactions of hydrocarbons

Dependent: Evidence for reaction
Independent: Temperature
  Time
  Light
  Concentrations
  Specific substrate
  Reagent

Note: This investigation has been listed for planning (b) only because the teacher will probably have to give information to the class about the relevant variables. This experiment has been carried out testing the possible reactions of bromine solution and the acid-catalysed addition of water to cyclohexane, cyclohexene, chlorobenzene, and methylbenzene. Any of the first four variables could be investigated.

2. Investigate how the densities of specified solutions vary with their concentrations

Dependent: Mass of solution
Independent: Concentration of solution
  Method of dilution
  Volume of solution

Note: Only concentration of the solution will be varied. The challenge is to keep volumes constant by dilution in a volumetric flask, rather than dilution by adding known volumes of solvent and solution.

3. Determine the molar mass of a gas

Dependent: Mass
Independent: Volume
  Temperature
  Pressure

Note: Probably no variable will be manipulated.

4. Determine the molar mass of a volatile liquid

Dependent: Mass
Independent: Identity of liquid
  Quantity of liquid
  Temperature
  Pressure

Note: Probably no variable will be manipulated.

5. Design a hot or cold pack to specifications

Dependent: Temperature change
Independent: Identity of chemical
  Quantity of chemical
  Quantity of water
  Original temperature

Note: This would probably be done by varying the quantity of chemical or water, and keeping other factors constant.

6. Determine the enthalpy of a reaction by a Hess's law relationship

Dependent: Temperature change
Independent: Nature of reactions
  Quantities of reactants
  Pressure
  Method of measurement

Note: The independent variables have to be controlled, rather than varied.

7. Determine the order of a reaction with respect to a specified reagent

Dependent: Change of concentration
Independent: Total volume of solution
  Concentration of reagent A
  Concentration of reagent B
  Temperature

Note: One concentration can be varied while other factors are kept constant.

8. Investigate the temperature of a Bunsen burner flame

Dependent: Temperature (relative rather than absolute)
Independent: Method of measurement
  Location of measurement
  Amount of gas
  Relative amounts of gas and air

Note: Several factors could be varied, but they would be difficult to measure.

9. Investigate the concentration ranges in which starch and iodine react

Dependent: Evidence for reaction
Independent: Relative concentrations of starch and iodine
  Presence of other substances
  Temperature
  Time

Note: Candidates are likely to change the first independent variable.

10. Investigate the conditions for glucose oxidase to react with glucose

Dependent: Measured effect
Independent: Measurement method
  Concentration of glucose
  Time
  Temperature
  Quantity of solution
  Presence of other substances in solution

Note: Candidates are likely to investigate the concentration necessary for reaction.

11. Investigate the relationship between the strength of an egg shell and its composition

Dependent: Measurement of strength
Independent: Method of measurement
  Different eggs
  Size of sample portion
  Analysis of composition

Note: Candidates will control variables rather than manipulate them.

12. Investigate the composition of a common substance by acid–base titration

Dependent: Volume of titrant
Independent: Identity of analyte
  Quantity of sample
  Concentration of titrant
  Indicator

Note: Candidates will control variables and specify their values rather than manipulate them.

13. Investigate the composition of a common substance by oxidation–reduction titration

Variables and evaluation are similar to investigation 12 above.

14. Investigate how the colour produced by iron(III) and thiocyanate ions varies with concentrations

Dependent: Absorbance
Independent: Wavelength
  Concentration of Fe(III) ions
  Concentration of thiocyanate ions
  Identity of complex formed

Note: Candidates will probably vary one concentration or the other, while keeping other
variables constant.

Note: In addition to the candidate work, samples submitted for moderation must include the instructions, written or oral, given to the candidate by the teacher. This vital information is used by moderators to assess whether the experiment, as given, was suitable for assessing the criteria.

back to top     back to contents