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Planning (a) and (b) in Chemistry Internal Assessment
The following list of investigation titles is divided into two groups:
- experiments suitable for planning (a) and
(b)
- experiments suitable for planning (b) only.
For each title, a list of the possible variables is included. Experiments
suitable for planning (a) have at least two independent variables
that could be manipulated during an investigation. The titles are sufficiently
specific to give candidates a sense of direction, but they are not sufficiently
specific to serve as a research question. Candidates will have to modify
the statement to make it more specific and focused. In most cases, this
will involve indicating the variable(s) chosen for investigation. Where
the title completely specifies the problem, and only one or no variables
can be manipulated, the experiment is listed for planning (b) only.
If the experiment is to be used to assess planning (a), candidates
should not be given information about the possible variables, since
one aspect of planning (a) concerns the candidate's ability to
select the relevant variables without help from the teacher.
Variables are things we measure, control or manipulate in an investigation.
Independent variables are those that are manipulated, whereas dependent
variables are measured or registered. The variable that is selected for
manipulation is independent, the variable that depends on the manipulation
is dependent. Thus, in a calorimetry investigation, where a candidate
measures the temperature every 30 seconds, time is the independent variable,
and temperature is the dependent variable. Similarly, in a rate investigation,
where the candidate measures the times taken to collect certain volumes
of gas, volume is independent, and time is dependent.
Investigations Suitable for Planning (a) and (b)
Click
here for a description of the planning criteria.
1. Investigate the volume of a drop
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| Dependent: |
Volume or mass of liquid |
| Independent: |
Nature of liquid, includes mass, density, viscosity (these cannot
be separated) |
| |
Temperature |
| |
Material of dropper |
| |
Size of opening |
| |
Angle of delivery |
| |
Speed of delivery |
| |
Height of water column |
| |
Pressure (external) |
Note: This is a very simple experiment
suitable as a first exposure to practise the skills associated with planning
(a) and (b). Any of the first seven independent variables can
be investigated.
2. Investigate the height of a liquid in a capillary tube
|
| Dependent: |
Height of liquid |
| Independent: |
Nature of liquid |
| |
Diameter of tube |
| |
Material of tube |
| |
Angle of tube |
| |
Temperature |
| |
Overall length of tube |
| |
Depth of capillary tube in the liquid |
Note: Suitable for practice for planning
(a) and (b). Any of the independent variables could be tested.
3. Investigate factors influencing the solubility of salts
|
| Dependent: |
Mass of solute |
| Independent: |
Volume or mass of water |
| |
Temperature |
| |
Anion |
| |
Cation |
| |
Relation of charges of the ions |
Note: Candidates will probably control
the first independent variable and can manipulate any of the last three.
4. Investigate the catalysed decomposition of hydrogen peroxide
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| Dependent: |
Some measure of change of concentration of a reactant
or product (volume of gas, decrease in mass, or concentration of hydrogen
peroxide) |
| Independent: |
Relative quantity of catalyst |
| |
Concentration of hydrogen peroxide |
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Other transition metal oxides |
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Other manganese compounds |
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Oxides or metals |
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State of division |
| |
Heterogeneous or homogeneous catalysis |
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Temperature |
Note: Temperature will probably be controlled.
Any of the other independent variables can be investigated.
5. Investigate exposure to radiation
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| Dependent: |
Counts per unit time |
| Independent: |
Type of radiation |
| |
Type of barrier |
| |
Thickness of barrier |
| |
Distance between source and detector |
| |
Strength of magnetic field |
| |
Angle between detector and source |
| |
Time of counting |
| |
Temperature |
Note: Any of the independent variables
can be easily manipulated, apart from temperature which will probably be
controlled.
6. Investigate the rate of electroplating a metal
|
| Dependent: |
Quantity of metal deposited |
| Independent: |
Time |
| |
Temperature |
| |
Concentration of solution |
| |
Identity of metal |
| |
Size of electrode |
| |
Voltage |
| |
Current |
Note: Any of the independent variables
could be investigated.
7. Investigate the
equilibrium reaction between an alkanoic acid and an alkanol |
| Dependent: |
Quantity of ester (or change in concentration
of acid or alkanol) |
| Independent: |
Initial concentrations of acid and alkanol |
| |
Time elapsed |
| |
Temperature |
| |
Nature of acid |
| |
Nature of alkanol |
| |
Method of measurement |
Note: Any of the first five independent
variables could be manipulated, but this presents a difficult and time-consuming
experiment. It would be easier for the teacher to direct the candidates
to measure the amounts of acid, and to grade this for planning (b)
only.
8. Investigate the effect of acid rain on building materials
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| Dependent: |
Effect on material |
| Independent: |
Type of material |
| |
Time of exposure |
| |
Surface area exposed |
| |
Method of measurement |
| |
Temperature |
| |
Nature of acid |
| |
Concentration of acid |
| |
Nature of exposure |
Note: Any of the independent variables
could be investigated.
9. Investigate
the conditions affecting the rate of escape of carbon dioxide from
soda water |
| Dependent: |
Quantity of gas released |
| Independent: |
Time |
| |
Temperature |
| |
Amount of soda water |
| |
Depth of soda water |
| |
Surface area of soda water |
| |
Material of container |
| |
Extent of agitation of the soda water |
| |
Pressure |
Note: Any of the first seven independent
variables could be investigated.
10. Investigate the amount of a solid that will dissolve in a
solvent
|
| Dependent: |
Quantity of solid |
| Independent: |
Nature of solid |
| |
Quantity of solvent |
| |
Nature of solvent |
| |
Time |
| |
Order of addition |
| |
Temperature |
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Stirring |
| |
State of division |
Note: Any of the independent variables
could be investigated. The effect of the last three is probably known
in advance.
11. Investigate the factors influencing the voltage of an electrochemical
cell
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| Dependent: |
Voltage |
| Independent: |
Size of electrodes |
| |
Distance between electrodes |
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Nature of electrodes |
| |
Nature of solution |
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Concentration of solution |
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Method of measurement |
| |
Nature of ion transfer (salt bridge) |
Note: Any of the first five independent
variables could be investigated.
12. Investigate the factors affecting retention in paper chromatography
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| Dependent: |
Distance travelled by spot |
| Independent: |
Thickness of paper |
| |
Nature of paper |
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Eluting solvent |
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Size of spot |
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Concentration of solute |
| |
Distance solvent travels |
| |
Nature of solute |
| |
Temperature |
Note: Any of the first six independent
variables could be manipulated.
13. Investigate testing the energy from liquid fuels
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| Dependent: |
Temperature change of water |
| Independent: |
Construction of calorimeter
(including nature of water container, amount and location of insulation,
supply of oxygen) |
| |
Type of fuel |
| |
Amount of fuel/time of burning |
| |
Amount of water |
| |
Distance of flame from calorimeter |
Note: The first set of independent
variables will be manipulated, and perhaps also the type of fuel. The
last three independent variables will need to be controlled.
14. Investigate the factors affecting the rate of a reaction
|
| Dependent: |
Change in concentration |
| Independent: |
Nature of reaction |
| |
Concentration of reagents |
| |
Total volume |
| |
Temperature |
| |
State of division (only for heterogeneous reaction) |
| |
Catalysis |
Note: Once a candidate chooses a reaction,
at least two other independent variables could be manipulated.
15. Determine a property of a gas
|
| Dependent: |
Measurements |
| Independent: |
Property investigated |
| |
Temperature |
| |
Volume |
| |
Pressure |
| |
Amount of gas |
Note: The property chosen should be
one where a variable can be changed. Candidates should have to devise
their own methods, rather than following familiar techniques.
16. Investigate
the factors that affect the rate of the reaction between sodium thiosulfate
and hydrochloric acid |
| Dependent: |
Time for visual change |
| Independent: |
Total volume of solution |
| |
Concentration of sodium thiosulfate |
| |
Concentration of hydrochloric acid |
| |
Temperature |
Note: Several variables could be manipulated.
This is a very simple variation on investigation 14 (above).
Investigations Suitable for Planning (b) Only
1. Investigate reactions of hydrocarbons
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| Dependent: |
Evidence for reaction |
| Independent: |
Temperature |
| |
Time |
| |
Light |
| |
Concentrations |
| |
Specific substrate |
| |
Reagent |
Note: This investigation has been listed
for planning (b) only because the teacher will probably have to
give information to the class about the relevant variables. This experiment
has been carried out testing the possible reactions of bromine solution
and the acid-catalysed addition of water to cyclohexane, cyclohexene,
chlorobenzene, and methylbenzene. Any of the first four variables could
be investigated.
2. Investigate how the densities of specified solutions vary with
their concentrations
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| Dependent: |
Mass of solution |
| Independent: |
Concentration of solution |
| |
Method of dilution |
| |
Volume of solution |
Note: Only concentration of the solution
will be varied. The challenge is to keep volumes constant by dilution
in a volumetric flask, rather than dilution by adding known volumes of
solvent and solution.
3. Determine the molar mass of a gas
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| Dependent: |
Mass |
| Independent: |
Volume |
| |
Temperature |
| |
Pressure |
Note: Probably no variable will be
manipulated.
4. Determine the molar mass of a volatile liquid
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| Dependent: |
Mass |
| Independent: |
Identity of liquid |
| |
Quantity of liquid |
| |
Temperature |
| |
Pressure |
Note: Probably no variable will be
manipulated.
5. Design a hot or cold pack to specifications
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| Dependent: |
Temperature change |
| Independent: |
Identity of chemical |
| |
Quantity of chemical |
| |
Quantity of water |
| |
Original temperature |
Note: This would probably be done by
varying the quantity of chemical or water, and keeping other factors constant.
6. Determine the enthalpy of a reaction by a Hess's law relationship
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| Dependent: |
Temperature change |
| Independent: |
Nature of reactions |
| |
Quantities of reactants |
| |
Pressure |
| |
Method of measurement |
Note: The independent variables have
to be controlled, rather than varied.
7. Determine the order of a reaction with respect to a specified
reagent
|
| Dependent: |
Change of concentration |
| Independent: |
Total volume of solution |
| |
Concentration of reagent A |
| |
Concentration of reagent B |
| |
Temperature |
Note: One concentration can be varied
while other factors are kept constant.
8. Investigate the temperature of a Bunsen burner flame
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| Dependent: |
Temperature (relative rather
than absolute) |
| Independent: |
Method of measurement |
| |
Location of measurement |
| |
Amount of gas |
| |
Relative amounts of gas and
air |
Note: Several factors could be varied,
but they would be difficult to measure.
9. Investigate the concentration ranges in which starch and iodine
react
|
| Dependent: |
Evidence for reaction |
| Independent: |
Relative concentrations of
starch and iodine |
| |
Presence of other substances |
| |
Temperature |
| |
Time |
Note: Candidates are likely to change
the first independent variable.
10. Investigate the conditions for glucose oxidase to react with
glucose
|
| Dependent: |
Measured effect |
| Independent: |
Measurement method |
| |
Concentration of glucose |
| |
Time |
| |
Temperature |
| |
Quantity of solution |
| |
Presence of other substances
in solution |
Note: Candidates are likely to investigate
the concentration necessary for reaction.
11. Investigate
the relationship between the strength of an egg shell and its composition |
| Dependent: |
Measurement of strength |
| Independent: |
Method of measurement |
| |
Different eggs |
| |
Size of sample portion |
| |
Analysis of composition |
Note: Candidates will control variables
rather than manipulate them.
12. Investigate the composition of a common substance by acidbase
titration
|
| Dependent: |
Volume of titrant |
| Independent: |
Identity of analyte |
| |
Quantity of sample |
| |
Concentration of titrant |
| |
Indicator |
Note: Candidates will control variables
and specify their values rather than manipulate them.
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13. Investigate the composition of a common substance by oxidationreduction
titration |
| Variables and evaluation are similar to investigation 12 above. |
14. Investigate how the colour produced by iron(III) and thiocyanate
ions varies with concentrations
|
| Dependent: |
Absorbance |
| Independent: |
Wavelength |
| |
Concentration of Fe(III) ions |
| |
Concentration of thiocyanate ions |
| |
Identity of complex formed |
Note: Candidates will probably vary
one concentration or the other, while keeping other
variables constant.
Note: In addition
to the candidate work, samples submitted for moderation must include the
instructions, written or oral, given to the candidate by the teacher.
This vital information is used by moderators to assess whether the experiment,
as given, was suitable for assessing the criteria.
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